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On the oxidation of saturated hydrocarbons with H2O2 in the presence of iron(II)-picolinate or iron(II)−1,10 phenanthroline 2-carboxylate.

✍ Scribed by G. Balavoine; D.H.R. Barton; J. Boivin; A. Gref

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
261 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

A new catalytic system for highly selective oxidation of saturated hydrocarbons into ketones is described. This system is based on the combination offerrous picolinate (or l,lOphenanthroline 2-carboqylate) and H202 in pyridine sohuion.Under these conditions cyclohexane gave mabdy cyclohmanone (90% ,22-28% yield based on H202 ) and minor amounts qf cyclohexanol .

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