Silica-gel containing H 2 O 2 or ROOH transforms vinyl alkyl or vinyl aryl ethers into the corresponding a-alkoxy hydroperoxides and dialkyl peroxides under very mild reaction conditions.
Oxidation of ethers by nitrogen dioxide in the presence of silica gel
β Scribed by Nishiguchi, Takeshi; Okamoto, Hiroaki
- Book ID
- 120885081
- Publisher
- The Royal Society of Chemistry
- Year
- 1990
- Tongue
- English
- Weight
- 149 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-4936
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π SIMILAR VOLUMES
Uiethylhydroxylamine, (CzH&NOH, was oxidized by NO2 a t 25Β°C in a long-path-length infrared gas cell. The measured products of the reaction were HONO and CH3CHO. The reaction scheme which explains the reaction is ## / O C,H,N=CHCH, + (C,H,),NOadduct with k 3 = (5.5 f 1.0) X 10-18 cm3/s, kq N 2.5
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