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The oxidation of diethylhydroxylamine by nitrogen dioxide

โœ Scribed by Jeffrey Gleim; Julian Heicklen

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
483 KB
Volume
14
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

Uiethylhydroxylamine, (CzH&NOH, was oxidized by NO2 a t 25ยฐC in a long-path-length infrared gas cell. The measured products of the reaction were HONO and CH3CHO. The reaction scheme which explains the reaction is

/ O

C,H,N=CHCH, + (C,H,),NOadduct with k 3 = (5.5 f 1.0) X 10-18 cm3/s, kq N 2.5 X experiments the nitrone cm3/s, and k l / k s = 0.30. In separate was oxidized by NO2, and the reaction was found to be very rapid with k > cm3/s. The products of the reaction were verified by both infrared absorption (CHzCHO, CZHSNO) and gas chromatography (CH3CH0, NO).

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