Oxidation of bis(Trimethylsilyl)amidodifluorophosphite
β Scribed by S. A. Lermontov; N. V. Sukhova; I. V. Martynov
- Book ID
- 112446898
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 137 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Anodic oxidation of a,cz'-bis(trimethylsilyl)-o-, -m-, and -p-xylenes (l-3) was comparativety examined. a-Trimethyliilylation of xylenes markedly decreased their oxidation potentials while additional a'trimethylsilylation resulted in no further change. The silylxylenes I-3 underwent anodic alkoxylat
Although the nucleophilicity/basicity at the phosphorus atom of the tetraphosphacubane 2 is reduced, apparently owing to the participation of the lone pairs of electrons in the PIC u bonds, stepwise oxidation of the phosphoms atoms with bis(trimethylsily1) peroxide or sulfur (in the presence of trie