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Structural isomerization of (bis(trimethylsilyl)amino)phosphine oxides

โœ Scribed by Neilson, Robert H.; Jacobs, Richard D.; Scheirman, Russell W.; Wilburn, James C.


Book ID
118040202
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
415 KB
Volume
17
Category
Article
ISSN
0020-1669

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## Abstract A series of naphthalenediylโ€1,8โ€bis(phosphine oxides) 1โ€RRโ€ฒP(:O)(C~10~H~6~)โ€8โ€P(:O)RRโ€ฒ (R = Rโ€ฒ = Me (2a), Et (2b), iPr (2c), Cy (2d), Ph (2f) and R = tBu, Rโ€ฒ = Ph (2e) was prepared by oxidation of the corresponding bis(phosphines) 1aโ€“f with molecular oxygen or H~2~O~2~ยท(H~2~N)~2~C(:O) a