Oxidation of aniline and some para-substituted anilines by benzimidazolium fluorochromate in aqueous acetic acid medium – A kinetic and mechanistic study
✍ Scribed by Sheik Mansoor, S.; Syed Shafi, S.
- Book ID
- 122307478
- Publisher
- Elsevier
- Year
- 2014
- Tongue
- English
- Weight
- 838 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1878-5352
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## Abstract The imidazolium fluorochromate (IFC) oxidation of __meta__‐ and __para__‐substituted anilines, in seven organic solvents, in the presence of __p__‐toluenesulfonic acid (TsOH) is first order in IFC and TsOH and is zero order with respect to substrate. The IFC oxidation of 15 __meta__‐ an
## Abstract The kinetics of oxidation of some monosaccharides viz., D‐ribose, D‐xylose, and D‐arabinose, D‐glucose, D‐fructose, D‐galactose, 2‐deoxyglucose, and α‐methyl glucopyranoside by MnO~4~^2−^ in aqueous alkaline medium have been studied. The rate of oxidation has been found to be first‐orde