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Oxidation of Some α-Amino Acids by Pyridinium Bromochromate in an Aquo-Acetic Acid Medium—A Kinetic and Mechanistic Study

✍ Scribed by N. Nalwaya; A. Jain; B.L. Hiran


Book ID
111597203
Publisher
Springer
Year
2004
Tongue
English
Weight
86 KB
Volume
45
Category
Article
ISSN
0023-1584

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## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by tetraethylammonium chlorochromate (TEACC) in dimethylsulfoxide leads to the formation of corresponding oxoacids. The reaction is first order each in TEACC and hydroxy acids. Reaction is failed to induce th

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The kinetics of oxidation of some neutralized ␣-hydroxy compounds such as glycolic (GA), lactic (LA), ␣-hydroxyisobutyric(IB), mandelic (MA), atrolactic (AL), and benzilic (BA) acids by tetrachloroaurate(III) have been studied. The substrates are oxidized to give formaldehyde, acetaldehyde, acetone,