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Oxidation of alkylhydrazines by iodine

โœ Scribed by Brown, Daniel M.; Jones, Gordon H.; Looker, Brian E.; McLean, Colin D.; Middleton, Sydney


Book ID
121321515
Publisher
Royal Society of Chemistry
Year
1977
Weight
587 KB
Volume
18
Category
Article
ISSN
1472-7781

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We have now prepared the ozonide (4), which appears to be an ideal starting material for the synthesis of (2). Compound ( 4 ) [m.p. 142ยฐC; NMR (CCl,): ~= 8 . 6 0 (6H), 8.73 (3H), 8.77 (3H), 9.07 (6H), 9.20 (6H)] is formed surprisingly smoothly by the action of AgBF, on the valence-isomeric ozonide (