Kinetics of oxidation of thiocyanate ion (NCS-) by iodine monochloride and iodine has been studied in aqueous perchloric acid medium. The rates of oxidations followed the rate laws: Variations in ionic strength and dielectric constant of the medium had little effects on the rates of reactions with
Mechanism of positive iodine reactions: Kinetics of oxidation of semicarbazide by iodamine-T, iodine monochloride and iodine
โ Scribed by B. Thimme Gowda; J. Ishwara Bhat
- Book ID
- 112906803
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1988
- Tongue
- English
- Weight
- 459 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0253-4134
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Studies of the stoichiometry and kinetics of the reaction between hydroxylamine and iodine, previously studied in media below pH 3, have been extended to pH 5.5. The stoichiometry over the pH range 3.4-5.5 is 2NHzOH and k l , kz, Kp, and KI are (6.5 2 0.6) x lo5 M-' s-', (5.0 2 0.5) s-', 1 x lo6 M-
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