✦ LIBER ✦

Kinetic study of the electrophilic reaction of trialkyltin chlorides and iodine monochloride

✍ Scribed by P. Verbiest; L. Verdonck; G. P. Van Der Kelen

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 295 KB
Volume: 25
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550250206

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✦ Synopsis

The kinetics of the eledrophilic substitution of several trialkyltin chlorides by iodine monochloride are presented. Rate constants have been determined at four different temperatures and the activation parameters A, En, and AS"= are calculated. A mechanism is proposed involving charge-transfer as the driving force for the substitution. 0 1993 John Wiley &. Sons. Inc.

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