Determination of formates by oxidation with iodine
β Scribed by R.M. Verma; Sameer Bose
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 272 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0003-2670
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π SIMILAR VOLUMES
A new calorimetric method for the determination of hydroxamic acid is described. Hydroxamic acid was oxidized quantitatively by iodine to produce nitrous acid, which was thereafter determined according to the diazocoupling reaction. This method is sensitive to as little as 5 nmol of hydroxamic acid,
The iodine value (iodine number) is an important analytical characteristic of fats and oils. Leading pharmacopeias determine it using iodine monobromide (Hanus method). We used methyl oleate as a simple analog of unsaturated triacylglycerols to identify the products. After performing the reaction in
Kinetics of oxidation of thiocyanate ion (NCS-) by iodine monochloride and iodine has been studied in aqueous perchloric acid medium. The rates of oxidations followed the rate laws: Variations in ionic strength and dielectric constant of the medium had little effects on the rates of reactions with