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Oxidation of alcohols with hydrogen peroxide catalyzed by soluble iron and osmium derivatives

✍ Scribed by Shul'pina, Lidia S. ;Veghini, Dario ;Kudinov, Aleksandr R. ;Shul'pin, Georgiy B.


Publisher
Springer
Year
2006
Tongue
English
Weight
69 KB
Volume
88
Category
Article
ISSN
0133-1736

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Selective oxidation of secondary and benzylic alcohols was efficiently accomplished by H 2 O 2 under solvent-free condition catalyzed by FeBr 3 . Secondary alcohols are selectively oxidized even in the presence of primary ones. This method is high yielding, safe and operationally simple.