Recent reports from this laboratory have described a new process for alcohol + carbonyl conversion which can be represented by Scheme A.
Oxidation of alcohols using dimethyl sulfoxide and trichloromethyl chloroformate
β Scribed by Seiichi Takano; Kohei Inomata; Shun'ichi Tomita; Masashi Yanase; Kiyohiro Samizu; Kunio Ogasawara
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 108 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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A new method for the synthesis of thioaldehyde and thioketone S-oxides by an unusual base-induced I~-elimination of chloroform from readily available aUylic and bcnzylic trichloromethyl sulfoxides is described. The reaction proceeds smoothly under mild conditions. The facile preparation of cx,13-uns
In the dimethyl sulfoxide (DMSO)-metal oxide oxidation of alcohol to carbonyl compound, molybdenum oxides were the only useful catalytic reagents, ant various alcohols were oxidized to the corresponding carbonyl compounds in high yields.