In view of the recent report on sulfoxonium salt oxidants, 1 we wish to report our investigations concerning dimethylsulfide ditriflate, which grew out of recent work in our laboratory centered on the exceptionally strong electron-withdrawing capabilities of the trifluoromethane sulfonyl ("trifyl")
โฆ LIBER โฆ
Dimethyl sulfoxide-catalytic molybdenum peroxide: A new system for the facile oxidation of alcohols
โ Scribed by Yoshiro Masuyama; Akira Tsuhako; Yasuhiko Kurusu
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 253 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
In the dimethyl sulfoxide (DMSO)-metal oxide oxidation of alcohol to carbonyl compound, molybdenum oxides were the only useful catalytic reagents, ant various alcohols were oxidized to the corresponding carbonyl compounds in high yields.
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