Dimethyl sulfide ditriflate: A new reagent for the facile oxidation of alcohols
β Scribed by James B. Hendrickson; Steven M. Schwartzman
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 189 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In view of the recent report on sulfoxonium salt oxidants, 1 we wish to report our investigations concerning dimethylsulfide ditriflate, which grew out of recent work in our laboratory centered on the exceptionally strong electron-withdrawing capabilities of the trifluoromethane sulfonyl ("trifyl") group. 2,3
π SIMILAR VOLUMES
In the dimethyl sulfoxide (DMSO)-metal oxide oxidation of alcohol to carbonyl compound, molybdenum oxides were the only useful catalytic reagents, ant various alcohols were oxidized to the corresponding carbonyl compounds in high yields.
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