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Oxidation of alcohols by “activated” dimethyl sulfoxide. a preparative, steric and mechanistic study

✍ Scribed by Kanji Omura; Daniel Swern

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
947 KB
Volume
34
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES

Oxidation studies with peroxomonophospho
Oxidation studies with peroxomonophosphoric acid. II. A kinetic and mechanistic study of dimethyl sulfoxide oxidation in acid and alkaline media
✍ G. P. Panigrahi; Radhasyam Panda 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB 👁 1 views

The kinetics of dimethyl sulfoxide (DMSO) oxidation by peroxomonophosphoric acid (PMPA) in aqueous medium a t 308 K and I = 0.4 mol/dm3 follow the rate expressions In the pH range from 0 to 2, where k l and kz are 5.092 X 10-1 dm3/mol sec and = 0, respectively; in the pH range from 4 to 7, where k2