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Oxidation of 1-acetyl-1-cyclohexene with molecular oxygen

✍ Scribed by A. A. Akhrem; A. M. Moiseenkov

Book ID
112490938
Publisher
Springer
Year
1968
Tongue
English
Weight
49 KB
Volume
17
Category
Article
ISSN
1573-9171

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Catalytic oxidation of 1-hexene and cycl
Catalytic oxidation of 1-hexene and cyclohexene with molecular oxygen by iridium nitro complexes
✍ P.J Baricelli; V.J SΓ‘nchez; A.J Pardey; S.A Moya πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 163 KB

The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 β€’ C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1