Polyvanadate-exchanged hydrotalcites as catalysts for selective oxidation of cyclohexene with molecular oxygen
β Scribed by Bahranowski, K. ;Kooli, F. ;Poltowicz, J. ;Serwicka, E. M.
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 298 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0133-1736
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π SIMILAR VOLUMES
Metbylrhenium trioxide (MTO) was found to be a good catalyst for the oxidation of tertiary phospbines by molecular oxygen at room temperature. Evidence is given that an intermediate Re( V) compound -CH3Re0,, or the adduct CH,ReO, . O=PPh,is involved. The deoxygenation of epoxides, sulfoxides, N-oxid
Metal (Me: Fe, Co, Ni or Cu) containing Mg-Al hydrotalcite-type anionic clay catalysts have been prepared by adopting the "memory effect" of hydrotalcite and tested for Baeyer-Villiger oxidation of ketones. Mg-Al hydrotalcite was calcined to the mixed oxide and dipped in an aqueous solution of metal