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Sn-exchanged hydrotalcites as catalysts for clean and selective Baeyer–Villiger oxidation of ketones using hydrogen peroxide

✍ Scribed by Unnikrishnan R Pillai; Endalkachew Sahle-Demessie


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
124 KB
Volume
191
Category
Article
ISSN
1381-1169

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Sn[N(SO 2 C 8 F 17 ) 2 ] 4 catalyst was shown to give an excellent yield and selectivity in a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones by 35% aqueous hydrogen peroxide, a green, safe and cheap oxidant. Furthermore, the catalyst was completely recovered and r