✦ LIBER ✦

Tin(IV) bis(perfluoroalkanesulfonyl)amide complex as a highly selective Lewis acid catalyst for Baeyer–Villiger oxidation using hydrogen peroxide in a fluorous recyclable phase

✍ Scribed by Xiuhua Hao; Osamu Yamazaki; Akihiro Yoshida; Joji Nishikido

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 266 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01185-7

No coin nor oath required. For personal study only.

✦ Synopsis

Sn[N(SO 2 C 8 F 17 ) 2 ] 4 catalyst was shown to give an excellent yield and selectivity in a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones by 35% aqueous hydrogen peroxide, a green, safe and cheap oxidant. Furthermore, the catalyst was completely recovered and reused in the fluorous immobilized phase without loss of activity.

📜 SIMILAR VOLUMES

Tin(IV) Bis(perfluoroalkanesulfonyl)amid

Tin(IV) Bis(perfluoroalkanesulfonyl)amide Complex as a Highly Selective Lewis Acid Catalyst for Baeyer—Villiger Oxidation Using Hydrogen Peroxide in a Fluorous Recyclable Phase.

✍ Xiuhua Hao; Osamu Yamazaki; Akihiro Yoshida; Joji Nishikido 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 118 KB 👁 1 views

Recyclable and Selective Lewis Acid Cata

Recyclable and Selective Lewis Acid Catalysts for Transesterification and Direct Esterification in a Fluorous Biphase System: Tin(IV) and Hafnium(IV) Bis(perfluorooctanesulfonyl)amide Complexes.

✍ Xiuhua Hao; Akihiro Yoshida; Joji Nishikido 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 137 KB 👁 2 views

## Abstract For Abstract see ChemInform Abstract in Full Text.