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Catalytic oxidation of cyclohexene with molecular oxygen by polyoxometalate-intercalated hydrotalcites

✍ Scribed by Jun Guo; Qing Ze Jiao; Jian Ping Shen; Da Zhen Jiang; Guang Hui Yang; En Ze Min

Book ID
112412845
Publisher
Springer US
Year
1996
Tongue
English
Weight
264 KB
Volume
40
Category
Article
ISSN
1011-372X

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Catalytic oxidation of 1-hexene and cycl
Catalytic oxidation of 1-hexene and cyclohexene with molecular oxygen by iridium nitro complexes
✍ P.J Baricelli; V.J SΓ‘nchez; A.J Pardey; S.A Moya πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 163 KB

The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 β€’ C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1