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Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes

✍ Scribed by Peng, Hao; Lin, Aijun; Zhang, Yan; Jiang, Honglai; Zhou, Jiecong; Cheng, Yixiang; Zhu, Chengjian; Hu, Hongwen

Book ID
111952529
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
268 KB
Volume
2
Category
Article
ISSN
2155-5435

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✍ Hiromasa Mitsudera; Chao-Jun Li 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 349 KB

Copper-catalyzed trifluoromethylation via oxidative sp 3 C-H activation at the a-position of nitrogen in tetrahydroisoquinoline derivatives using DDQ and Ruppert-Prakash reagent has been successfully achieved. The reaction of various amines gave the corresponding trifluoromethylated products in 15-9