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Copper-catalyzed benzylic oxidation of C(sp3)–H bonds

✍ Scribed by Zhang, Bo; Zhu, Shou-Fei; Zhou, Qi-Lin

Book ID
120440408
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
365 KB
Volume
69
Category
Article
ISSN
0040-4020

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✍ Hiromasa Mitsudera; Chao-Jun Li 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 349 KB

Copper-catalyzed trifluoromethylation via oxidative sp 3 C-H activation at the a-position of nitrogen in tetrahydroisoquinoline derivatives using DDQ and Ruppert-Prakash reagent has been successfully achieved. The reaction of various amines gave the corresponding trifluoromethylated products in 15-9