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Copper-catalyzed benzylic C(sp3)–H alkoxylation of heterocyclic compounds

✍ Scribed by Takemura, Noriaki; Kuninobu, Yoichiro; Kanai, Motomu

Book ID
121673661
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
591 KB
Volume
12
Category
Article
ISSN
1477-0520

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Copper-catalyzed oxidative trifluorometh
Copper-catalyzed oxidative trifluoromethylation of benzylic sp3 C–H bond adjacent to nitrogen in amines
✍ Hiromasa Mitsudera; Chao-Jun Li 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 349 KB

Copper-catalyzed trifluoromethylation via oxidative sp 3 C-H activation at the a-position of nitrogen in tetrahydroisoquinoline derivatives using DDQ and Ruppert-Prakash reagent has been successfully achieved. The reaction of various amines gave the corresponding trifluoromethylated products in 15-9