Outer-sphere electron transfer in polar solvents
โ Scribed by L.D. Zusman
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 831 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We analyse outer-sphere electron transfer (ET) in a dielectric medium, which is characterised by a continuous distribution of dielectric relaxation times. An explicit expression for the averaged ET rate is derived in the particular case of the Davidson-Cole dielectric susceptibility function. A quan
The free energy change of an electron transfer reaction in a polar solvent is rigorously analyzed within the framework of the dielectric continuum model. An appropriate expression for the electrostatic energy between the two product ions separated by R is derived. The present result does not support