Outer-sphere electron-transfer reactions in model molecular solvents: the mean spherical approximation
โ Scribed by Yaoqi Zhou; Harold L. Friedman; George Stell
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 1006 KB
- Volume
- 152
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
The outer-sphere contribution to the volume of activation of homogeneous electron exchange reactions is estimated for selected solvents on the basis of the mean spherical approximation (MSA), and the calculated values are compared with those estimated by the Stranks-Hush-Marcus (SHM) theory and with
The electrode reaction of the C~(en):+'~+ couple on mercury electrodes in water-acetonitrile (AN), water-DMSO and water-hexamethylphosphortriamide (HMPT) mixed solvents has been investigated. The differences between Gibbs energies of transfer of the Co(en):+ and Co(en)$+ ions from water to mixtures