Estimation of the outer-sphere contribution to the activation parameters for homogeneous electron-transfer reactions using the mean spherical approximation

Estimation of the outer-sphere contribut

Estimation of the outer-sphere contribution to the activation volume for electron exchange reactions using the mean spherical approximation

✍ Hideo D. Takagi; Thomas W. Swaddle 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 433 KB

The outer-sphere contribution to the volume of activation of homogeneous electron exchange reactions is estimated for selected solvents on the basis of the mean spherical approximation (MSA), and the calculated values are compared with those estimated by the Stranks-Hush-Marcus (SHM) theory and with