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Osmium(VIII) mediated oxidation of mercury(I) by cerium(IV) in aqueous sulphuric acid – a kinetic and mechanistic study

✍ Scribed by Shivamurti A. Chimatadar; Sangappa B. Koujalagi; Sharanappa T. Nandibewoor


Book ID
110249089
Publisher
Springer
Year
2001
Tongue
English
Weight
109 KB
Volume
26
Category
Article
ISSN
0340-4285

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Ruthenium(III)-mediated oxidation of D-m
✍ Rajeshwari V. Hosahalli; Anita P. Savanur; Sharanappa T. Nandibewoor; Shivamurti 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB 👁 1 views

## Abstract The oxidation of D‐mannitol by cerium(IV) has been studied spectrophotometrically in aqueous sulfuric acid medium at 25°C at constant ionic strength of 1.60 mol dm^−3^. A microamount of ruthenium(III) (10^−6^ mol dm^−3^) is sufficient to enhance the slow reaction between D‐mannitol and