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Mechanistic study of iodide catalysed oxidation ofl-glutamic acid by cerium(IV) in aqueous sulphuric acid medium

✍ Scribed by Shivamurti A. Chimatadar; Shankar V. Madawale; Sharanappa T. Nandibewoor

Publisher: Springer
Year: 2007
Tongue: English
Weight: 387 KB
Volume: 32
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-007-0222-6

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## Abstract The oxidation of D‐mannitol by cerium(IV) has been studied spectrophotometrically in aqueous sulfuric acid medium at 25°C at constant ionic strength of 1.60 mol dm^−3^. A microamount of ruthenium(III) (10^−6^ mol dm^−3^) is sufficient to enhance the slow reaction between D‐mannitol and