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Mechanistic Study of Oxidation of Palladium(II) by Cerium(IV) in Aqueous Acid

✍ Scribed by Kiran A. Thabaj; Shivamurti A. Chimatadar; Sharanappa T. Nandibewoor

Publisher: Springer
Year: 2006
Tongue: English
Weight: 295 KB
Volume: 31
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-005-6366-3

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## The kinetics of the oxidation of p-methylmandelic acid (MMA) by ceric sulphate has been studied in aqueous sulphuric acid solutions and in H2S04-HC104 and H2S04-LiHS04 mixtures. In these mktures the observed rate law is: -d[Ce(IV)]/dt = k[MMA][Ce(IV)], where k = kl + k&l + a)' ## constant). Th