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Mechanistic study of cerium(IV) oxidation of antimony(III) in aqueous sulphuric acid in the presence of micro amounts of manganese(II) by stopped flow technique

โœ Scribed by Rudragouda K. Patil; Shivamurti A. Chimatadar; Sharanappa T. Nandibewoor

Publisher
Springer
Year
2008
Tongue
English
Weight
404 KB
Volume
33
Category
Article
ISSN
0340-4285

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Oxidation of vanillin by diperiodatocuprate(III) in aqueous alkaline medium: A kinetic and mechanistic study by stopped flow technique
โœ D. C. Hiremath; T. S. Kiran; S. T. Nandibewoor ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 286 KB ๐Ÿ‘ 1 views

## Abstract The kinetics of oxidation of vanillin (VAN) by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of 0.50 mol dm^โˆ’3^ was studied spectrophotometrically. The reaction between DPC and vanillin in alkaline medium exhibits 1:2 stoichiometry (vanillin: DPC). The re