Osmium(VIII) catalyzed oxidation of tellurium(IV) by periodate in aqueous alkaline medium
โ Scribed by Kembhavi, M. R. ;Harihar, A. L. ;Nandibewoor, S. T.
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 320 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0133-1736
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๐ SIMILAR VOLUMES
The osmium(VIII) catalysed IO2 oxidation of DMF in aqueous alkaline medium follows the rate law: where K2 is the equilibrium constant of the reaction K 3 is the formation constant for the complex between DMF and [OsOs(OH)] 3-and k is the decomposition rate constant. The data suggest that the oxida
Os(VIII) and Ru(III) catalysis of the periodate oxidation of acetaldehyde in aqueous alkaline medium was investigated. The catalytic efficiency is Ru(III) `Os(VIII). The product of oxidation in both cases is acetate and IO 3 ร . The stoichiometry is the same in both catalyzed reactions, i.e. [IO 4
## The kinetics of the osmium( VIII) catalyzed oxidation of Te(IV) by octacyanomolybdate( V) and octacyanotungstate(V) tins have been investigated in an alkaline medium. The reactions are first order with respect to M(CN)i-ion (M = MO, W) and catalyst concentrations. The second order reaction rate