Os(VIII) and Ru(III) catalysis of the periodate oxidation of acetaldehyde in aqueous alkaline medium was investigated. The catalytic efficiency is Ru(III) `Os(VIII). The product of oxidation in both cases is acetate and IO 3 Γ . The stoichiometry is the same in both catalyzed reactions, i.e. [IO 4
Ruthenium(III) catalyzed oxidation of hexacyanoferrate(II) by periodate in aqueous alkaline medium
β Scribed by Hiremath, G. A. ;Timmanagoudar, P. L. ;Nandibewoor, S. T.
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 241 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0133-1736
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π SIMILAR VOLUMES
The kinetics of the oxidation of cyclopentanol, cyclohexanol, 2-methylcyclohexanol, and cycloheptanol by hexacyanoferrate(II1) ions in mild alkaline medium has been studied in the presence of traces of ruthenium(V1) = lO-?M at constant ionic strength (0.26M). The results suggest that the oxidation o
The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ 6 ] and a compli
The oxidation kinetics of 2-butanol by alkaline hexacyanoferrate(III) catalyzed by sodium ruthenate has been studied spectrophotometrically. The initial rates method was used for kinetic analysis. The reaction rate shows a fractional-order in [hexacyanoferrate(III)] and [substrate] and a first-order