๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

A kinetic study of the osmium(VIII) catalyzed oxidation of tellurium(IV) by Octacyanomolybdate(V) and octacyanotungstate(V) ions in an alkaline medium

โœ Scribed by J.G. Leipoldt; C.R. Dennis; A.J. van Wyk; L.D.C. Bok

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
291 KB
Volume
34
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.

โœฆ Synopsis

The kinetics of the osmium( VIII) catalyzed oxidation of Te(IV) by octacyanomolybdate( V) and octacyanotungstate(V) tins have been investigated in an alkaline medium. The reactions are first order with respect to M(CN)i-ion (M = MO, W) and catalyst concentrations. The second order reaction rate

constants are 2.756 X lo3 M-' set-' and 5.221 X lo2 M-r set-' at 298 K respectively. A reaction mechanism is proposed.

๐Ÿ“œ SIMILAR VOLUMES

A kinetic study of the osmium(Vlll) cata
A kinetic study of the osmium(Vlll) catalyzed reduction of octacyanomolyb-date(V) and octacyanotungstate(V) ions by selenium(IV) in an alkaline medium
โœ G. Leipoldt; C.R. Dennis; A.J. Van Wyk; L.D.C. Bok ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 276 KB

## The kinetics of the osmium( VIII) catalyzed reduction of octacyanomolybdate( V) and octacyana tungstate(V) ions by Se(IV) have been studied in an alkaline medium. The reaction is first order with respect to M(CN)i-ions (M = MO, W) and the osmium( VIII) catalyst. The second order reaction rate c

Oxidation of primary amines by bromamine
Oxidation of primary amines by bromamine-B catalyzed by Osmium(VIII) in alkaline medium: A kinetic and mechanistic study
โœ S. Ananda; T. Demappa; N. M. Made Gowda ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 166 KB ๐Ÿ‘ 2 views

The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะŠC. In the presence of the catalyst, the experimental rate law

Ruthenium(III) catalysed oxidation of ga
Ruthenium(III) catalysed oxidation of gabapentin (neurontin) by diperiodatonickelate(IV) in aqueous alkaline medium: A kinetic and mechanistic study
โœ Chanabasayya V. Hiremath; Deepak C. Hiremath; Sharanappa T. Nandibewoor ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 404 KB

The kinetics of Ru(III) catalysed oxidation of neuroleptic drug, gabapentin by diperiodatonickelate(IV) (DPN) in alkaline medium at 298 K and a constant ionic strength of 0.30 mol dm -3 was studied spectrophotometrically. The oxidation products are 1-(hydroxymethyl) cyclohexane acetic acid and Ni(II