𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Original Synthesis of α-Chloroketones in Azaheterocyclic Series Using TDAE Approach.

✍ Scribed by Marc Montana; Thierry Terme; Patrice Vanelle

Publisher
John Wiley and Sons
Year
2006
Weight
23 KB
Volume
37
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Tetrakis(dimethylamino)ethylene (TDAE) a
Tetrakis(dimethylamino)ethylene (TDAE) as a useful reductant of some chlorodifluoromethylated ketones. A new approach for the synthesis of α,α-difluoroketone derivatives
✍ Conrad Burkholder; William R. Dolbier Jr; Maurice Me´debielle; Alexandre Ndedi 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 237 KB

Tetrakis(dimethylamino)ethylene (TDAE) was found to be an effective reductant of chlorodifluoromethylated ketones 1-3. The generated ~,~-difluoroacetyl anion was trapped with several aldehydes 4-7, under mild conditions, to give the corresponding 2,2-difiuoro-3-hydroxy ketone derivatives 8-13, in mo

ChemInform Abstract: Tetrakis(dimethylam
ChemInform Abstract: Tetrakis(dimethylamino)ethylene (TDAE) as a Useful Reductant of Some Chlorodifluoromethylated Ketones. A New Approach for the Synthesis of α,α-Difluoroketone Derivatives.
✍ C. BURKHOLDER; W. R. JUN. DOLBIER; M. MEDEBIELLE; A. NDEDI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Tetrakis(dimethylamino)ethylene (TDAE) as a Useful Reductant of Some Chlorodifluoromethylated Ketones. A New Approach for the Synthesis of α,α-Difluoroketone Derivatives. -Reduction of chlorodifluoromethylated ketones with TDAE as an effective reductant generates α,α-difluoroacetyl anions, which ar