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Origin of the pyramidalization of the tert-butyl radical

✍ Scribed by Paddon-Row, Michael N.; Houk, K. N.

Book ID
126187110
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
484 KB
Volume
103
Category
Article
ISSN
0002-7863

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## Abstract Analysis of the products from a vapor‐phase mixture of EtI and __t__‐BuI, in which free radicals were generated thermally, has yielded a rate constant for the recombination of 2__t__‐Buβ‹… of 10^5.4^ M^βˆ’1^ sec^βˆ’1^ at 100Β°C. The close agreement between this and other recent estimations fro