Organotin diphenylmonothiophosphinates. Crystal structure of bis(diphenylmonothiophosphinato) dimethyltin(IV), Me2Sn(OSPPh2)2
β Scribed by C. Silvestru; I. Haiduc; F. Caruso; M. Rossi; B. Mahieu; M. Gielen
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 789 KB
- Volume
- 448
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The diorganotin(IV) complexes, R 2 Sn(dtbu) (R = Me 1, n-Bu 2, Ph 3, PhCH 2 4; H 2 dtbu = 2,5-dithiobiurea), have been synthesized and characterized by IR, 1 H, and 119 Sn NMR spectroscopy. The structures of 1 and 3 have been determined by X-ray crystallography. Crystal structures show that both com
All reagents were of analytical grade and were used without further purification. R 3 SnCl (R = Me, n-Bu, C 6 H 11 and Ph) were of commercial origin; (PhCH 2 ) n SnCl 4 Οͺ n (n = 1, 2) were prepared by literature methods. Solvents were dried by standard procedures. Spectra were recorded on the foll
## Abstract A twoβdimensional layer structure is found in the title compound comprising interconnected 22βmembered rings and __trans__βC~3~O~2~ trigonal bipyramidal coordination geometries for tin. Copyright Β© 2003 John Wiley & Sons, Ltd.