Synthesis and characterization of di-and triorganotin(IV) diethyldithiophosphinates. The crystal and molecular structure of bis(diethyldithiophosphinato)dimethyltin(IV), Me2Sn(S2PEt2)2
β Scribed by Cristian Silvestru; Ionel Haiduc; Simona Klima; Ulf Thewalt; Marcel Gielen; J.J. Zuckerman
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 704 KB
- Volume
- 327
- Category
- Article
- ISSN
- 0022-328X
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All reagents were of analytical grade and were used without further purification. R 3 SnCl (R = Me, n-Bu, C 6 H 11 and Ph) were of commercial origin; (PhCH 2 ) n SnCl 4 Οͺ n (n = 1, 2) were prepared by literature methods. Solvents were dried by standard procedures. Spectra were recorded on the foll
The diorganotin(IV) complexes, R 2 Sn(dtbu) (R = Me 1, n-Bu 2, Ph 3, PhCH 2 4; H 2 dtbu = 2,5-dithiobiurea), have been synthesized and characterized by IR, 1 H, and 119 Sn NMR spectroscopy. The structures of 1 and 3 have been determined by X-ray crystallography. Crystal structures show that both com
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