C'hC'I72. Commun. 1987Commun. . 1223Commun. -1224. [I31 Die chemischc Verschiebung des "'Sn-Signals war charakteristisch temperaturabhiingig; das Slgnal verschob sich linear von 6 = 2068.5 be1 2 5 ' C zu 6 = 2090.5 bei -60°C (externer Standard [Cp,Sn] in T H F bei 25°C). Die Halbwertsbreite des Sign
Organometallic Titanium Complexes with Unpaired Electrons: Syntheses and Structures of [{(η5-Cp)2 TiF2}3 Ti] and [{(η5-Cp′)2 TiF2}3Al]
✍ Scribed by Dr. Feng-quan Liu; Dipl.-Chem. Heinz Gornitzka; Dr. Dietmar Stalke; Prof. Herbert W. Roesky
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 449 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
varied iteratively in the refinement until an equivalent isotropic displacement factor comparable with that at the other positions resulted. For each ring position in the disorder model so obtained the C:P ratio was fixed, an anisotropic displacement factor refined together with the atomic positions
The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,