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Organometallic Macrocycle Chemistry. 4. Synthesis and Reactions of [RuX(CS)(PPh3)([9]aneS3)]ClO4 (X = H, Cl, SCN, SC6H4Me-4; [9]aneS3 = 1,4,7-Trithiacyclononane)

✍ Scribed by Hector, Andrew L.; Hill, Anthony F.


Book ID
127050897
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
412 KB
Volume
34
Category
Article
ISSN
0020-1669

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Reactions of 1,4,7-trithiacyclononane, [
✍ Gerald R. Willey; Janet Palin; Miles T. Lakin; Nathaniel W. Alcock πŸ“‚ Article πŸ“… 1994 πŸ› Springer 🌐 English βš– 433 KB

The reactions of titanium(III) and (IV) chlorides with the crown thioether [93aneS3 were investigated. [TiCt 3-(MeCN)3 ] gives a purple 1:1 adduet with a proposed octahedral structure involving tridentate foe-attachment of the ligand. With [TiClg(MeCN)2] the identity of the yellow 1:1 adduct obtaine