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Synthesis, structure and reactivity of cationic rhodium(I) and iridium(I) thioether crowns: structures of [M([9]aneS3)(cod)]+(M = Rh, Ir; cod = cycloocta-1,5-diene) and [Rh([9]aneS3)(C2H4)2]+([9]aneS3= 1,4,7-trithiacyclononane)

✍ Scribed by Blake, Alexander J.; Halcrow, Malcolm A.; Schr�der, Martin


Book ID
126795093
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
471 KB
Volume
4
Category
Article
ISSN
0022-4936

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Thioether crown complexes as templates f
✍ Alexander J. Blake; Robert O. Gould; Wan-Sheung Li; Vito Lippolis; Simon Parsons 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 363 KB

Pd(II) and Pt(II) complexes of [16]aneS 4 and Pd(II) complexes of cis-(HO) 2 [14]aneS 4 and [9]aneS 3 have been used as templates for the selfassembly of polyiodide ions. The complexes {[M([16]aneS 4 )] 2 I}I 11 (M ϭ Pd, Pt), [Pd(cis-(HO) 2 [14]aneS 4 )](I 3 ) 2 , [Pd([9]aneS 3 ) 2 ](I x ) 2 (x ϭ 3,