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Synthesis of 16-Electron (η 3 -Cyclooctenyl)metallacarboranes of Rhodium(III) and Iridium(III) with the New Sterically Demanding [(4‘-MeC 6 H 4 ) 2 C 2 B 9 H 9 ] 2- Carborane Ligand. Molecular Structures of [3-{(1−3-η 3 )-C 8 H 13 }-1,2-(4‘-MeC 6 H 4 ) 2 -3,1,2- pseud ocloso -MC 2 B 9 H 9 ] (M = Rh, Ir) and [(η 6 -MeC 6 H 4 )Rh(C 2 B 9 H 9 C 6 H 4 Me)Rh(η 4 -C 8 H 12 )] 2 , a Dimeric Byproduct Containing Distorted 13-Vertex {4,9,1,10-Rh 2 C 2 B 9 } Cluster Units

✍ Scribed by Alekseev, Leonid S.; Dolgushin, Fedor M.; Korlyukov, Alexander A.; Godovikov, Ivan A.; Vorontsov, Evgenii V.; Chizhevsky, Igor T.

Book ID
127370883
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
236 KB
Volume
26
Category
Article
ISSN
0276-7333

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