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Mercury thioether chemistry: The synthesis and structure of [Hg([9]aneS3)2](PF6)2 ([9]aneS3 = 1,4,7-trithiacyclononane)

✍ Scribed by Alexander J. Blake; Alan J. Holder; Timothy I. Hyde; Gillian Reid; Martin Schröder


Book ID
108428116
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
448 KB
Volume
8
Category
Article
ISSN
0277-5387

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The reactions of titanium(III) and (IV) chlorides with the crown thioether [93aneS3 were investigated. [TiCt 3-(MeCN)3 ] gives a purple 1:1 adduet with a proposed octahedral structure involving tridentate foe-attachment of the ligand. With [TiClg(MeCN)2] the identity of the yellow 1:1 adduct obtaine