Reactions of 1,4,7-trithiacyclononane, [
✍
Gerald R. Willey; Janet Palin; Miles T. Lakin; Nathaniel W. Alcock
📂
Article
📅
1994
🏛
Springer
🌐
English
⚖ 433 KB
The reactions of titanium(III) and (IV) chlorides with the crown thioether [93aneS3 were investigated. [TiCt 3-(MeCN)3 ] gives a purple 1:1 adduet with a proposed octahedral structure involving tridentate foe-attachment of the ligand. With [TiClg(MeCN)2] the identity of the yellow 1:1 adduct obtaine