𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Organolithium substitution at a bicyclo[1.1.0]butane bridgehead position. Evidence for a bicyclo[1.1.0]but-1(3)-ene as a reaction intermediate

✍ Scribed by Szeimies, Guenter; Harnisch, Joachim; Baumgaertel, Otto


Book ID
126177151
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
267 KB
Volume
99
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Formal Alder-ene reaction of a bicyclo[1
✍ Masafumi Ueda; Maciej A.A. Walczak; Peter Wipf πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 French βš– 262 KB

A tricyclic substructure of the tetracyclic nitrogen core of the daphniglaucins was formed by an oxidative activation of the allyl side chain of a bicyclo[1.1.0]butylmethylamine, a spontaneous intramolecular formal Alder-ene reaction, and a selective cyclization of a triol intermediate.