✦ LIBER ✦

Formal Alder-ene reaction of a bicyclo[1.1.0]butane in the synthesis of the tricyclic quaternary ammonium core of daphniglaucins

✍ Scribed by Masafumi Ueda; Maciej A.A. Walczak; Peter Wipf

Book ID: 104095704
Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 262 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.07.179

No coin nor oath required. For personal study only.

✦ Synopsis

A tricyclic substructure of the tetracyclic nitrogen core of the daphniglaucins was formed by an oxidative activation of the allyl side chain of a bicyclo[1.1.0]butylmethylamine, a spontaneous intramolecular formal Alder-ene reaction, and a selective cyclization of a triol intermediate.

📜 SIMILAR VOLUMES

A study of orbital interactions in the r

A study of orbital interactions in the reactions of bicyclo[1.1.0]butane

✍ Hiroshi Fujimoto; Toshihide Yabuki; Kenichi Fukui 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 559 KB

Mechanism of the Cycloaddition of Bicycl

Mechanism of the Cycloaddition of Bicyclo[2.1.0]pent-2-ene: a Non-concerted Homo-Diels-Alder Reaction

✍ Prof. Dr. Frank-Gerrit Klärner; Dipl.-Chem. Manfred Naumann 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 266 KB 👁 2 views

A Simple Synthesis of Bicyclo [1.1.0]but

A Simple Synthesis of Bicyclo [1.1.0]butane and its Relation to the Internal Conversion of Electronic Energy in 1,3-Butadiene

✍ Srinivasan, R. 📂 Article 📅 1963 🏛 American Chemical Society 🌐 English ⚖ 277 KB

Application of the intramolecular wadswo

Application of the intramolecular wadsworth-emmons reaction to bicyclo[3.3.0]oct - Δ1,2 - en - 3 - ones. Synthesis and x-ray structure of a novel

✍ Michael J. Begley; Kelvin Cooper; Gerald Pattenden 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 686 KB

The first example of an intramolecular D

The first example of an intramolecular Diels–Alder furan (IMDAF) reaction of iminium salts and its application in a short and simple synthesis of the isoindolo[1,2-a]isoquinoline core of the jamtine and hirsutine alkaloids

✍ Fedor I. Zubkov; Julya D. Ershova; Vladimir P. Zaytsev; Mykola D. Obushak; Vasyl 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 436 KB

short and simple synthesis of the isoindolo[1,2-a]isoquinoline core of the jamtine and hirsutine alkaloids

ChemInform Abstract: The First Example o

ChemInform Abstract: The First Example of an Intramolecular Diels—Alder Furan (IMDAF) Reaction of Iminium Salts and Its Application in a Short and Simple Synthesis of the Isoindolo[1,2-a]isoquinoline Core of the Jamtine and Hirsutine Alkaloids.

✍ Fedor I. Zubkov; Julya D. Ershova; Vladimir P. Zaytsev; Mykola D. Obushak; Vasyl 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views