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The electronic structures of trans- and cis-bicyclo[4.1.0]hept-3-ene. Evidence for a twist, bent .sigma. bond

✍ Scribed by Dixon, David A.; Gassman, Paul G.


Book ID
126140841
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
297 KB
Volume
110
Category
Article
ISSN
0002-7863

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7-Methyl-frans-bicyclo[4LO]hept-3-ene has been synthesized and the thermal and transitionmetal-complex promoted rearrangements of trans-bicyclo[4.1.0]hept-3-ene, 7-methyl-franr-bicyclo[4.1.0]-hept3-ene, and 7,7-dimethyl-tranr-bicyclo[4.l.O]hept-3-ene have been compared.