Molecules with Twist Bent Bonds. A Comparison of the Thermal and Transition-Metal-Complex Promoted Rearrangements of st]Derivatives of trans-Bicyclo[4.1.0]hept-3-ene

✍ Scribed by Paul G. Gassman; Kata Mlinarić-Majerski

• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 239 KB
• Volume: 29
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)80613-9

✦ Synopsis

7-Methyl-frans-bicyclo[4LO]hept-3-ene has been synthesized and the thermal and transitionmetal-complex promoted rearrangements of trans-bicyclo[4.1.0]hept-3-ene, 7-methyl-franr-bicyclo[4.1.0]-hept3-ene, and 7,7-dimethyl-tranr-bicyclo[4.l.O]hept-3-ene have been compared.