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Organoaluminum-promoted Claisen rearrangement of bisallyl vinyl ethers

✍ Scribed by Keiji Maruoka; Hiroshi Banno; Katsumasa Nonoshita; Hisashi Yamamoto

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 129 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72731-6

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✦ Synopsis

The Claisen rearrangement of bisally1 vinyl ethers with exceptionally bulky organoaluminum reagents exhibits unprecedented regiochemical control not observable in

the ordinary thezvtal rearrangement.

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