Organic-Solvent-Free Phase-Transfer Oxidation of Alcohols Using Hydrogen Peroxide
β Scribed by Hulce, Martin; Marks, David W.
- Book ID
- 118127028
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 92 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0021-9584
- DOI
- 10.1021/ed078p66
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π SIMILAR VOLUMES
Selective oxidation of secondary and benzylic alcohols was efficiently accomplished by H 2 O 2 under solvent-free condition catalyzed by FeBr 3 . Secondary alcohols are selectively oxidized even in the presence of primary ones. This method is high yielding, safe and operationally simple.
## Abstract For Abstract see ChemInform Abstract in Full Text.
A kinetic investigation of the Ru-catalyzed oxidation of I-phenyl ethanol to acetophenone using H\_O., under PT conditions shows that this system differs from classic extraction and interracial mechanisms often encountered in PTC oxidations. Vesicles formed by the phase transfer agent in the organic