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Organic Reactions under High Pressure. VII. Volumes of Activation for Some Diels-Alder Reactions

✍ Scribed by Walling, Cheves.; Schugar, Hervey J.


Book ID
126278145
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
845 KB
Volume
85
Category
Article
ISSN
0002-7863

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Organic reactions at high pressure. The
✍ William G. Dauben; William R. Baker πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 190 KB

The Diels-Alder reaction of e-benzoquinone with substituted dienoic esters affords good yields of 4a,5,8,8a-tetrahydro-1,4+aphthalenediones, free from the isomeric hydroquinone. The reactions were conducted at room temperature under 15 kbar (1.5 GPa) pressure in dichloromethane solutions.